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Ruthenium(III) Chloride Cas 10049-08-8

Function:

Ruthenium trichloride is a reddish-brown or black leaf-like crystal that is easily deliquescent. The relative density is 3.11, and it decomposes into elemental substances when it is higher than 500 °C. Insoluble in cold water and carbon disulfide, decomposed in hot water, insoluble in ethanol, soluble in hydrochloric acid. It reacts with potassium iodide solution to generate iodide precipitation, which is precipitated as diruthenium trisulfide when hydrogen sulfide is introduced into the solution, and can form corresponding ammonia, cyanide, and nitroso compounds with complexing agents such as ammonia, potassium cyanide and potassium nitrite. The complex is reduced to blue divalent ruthenium ions with sodium amalgam or titanium trichloride.

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Product Name: Ruthenium(III) Chloride

Chemical Structure:

Specifications:

Item Specifications
CAS No 10049-08-8
Molecular Formula Cl3Ru
Molecular Weight 207.43
Appearance

 

Black Brown Solid

 

Raw material Ru

purity %

 

≥99.95 %

 

Ru Assay%

 

38 %- 36 %

 

Cu Assay%

 

< 0.0120

 

Ca Assay%

 

<0.0120

 

Mg Assay%

 

<0.0120

 

Na Assay%

 

<0.0120

 

Function: 

Ruthenium trichloride is a reddish-brown or black leaf-like crystal that is easily deliquescent. The relative density is 3.11, and it decomposes into elemental substances when it is higher than 500 °C. Insoluble in cold water and carbon disulfide, decomposed in hot water, insoluble in ethanol, soluble in hydrochloric acid. It reacts with potassium iodide solution to generate iodide precipitation, which is precipitated as diruthenium trisulfide when hydrogen sulfide is introduced into the solution, and can form corresponding ammonia, cyanide, and nitroso compounds with complexing agents such as ammonia, potassium cyanide and potassium nitrite. The complex is reduced to blue divalent ruthenium ions with sodium amalgam or titanium trichloride.

 

Application:

  1. Used as a spectrally pure reagent
  2. A catalyst for the oxidative cyclization of 1,7-diene to oxepanediol.The tertiary carbon-hydrogen bonds of the cyclic ethers are hydroxylated with periodate or bromate.

 

 Shippment

Packing:1kg or 0.5kg bag

Delivery: 7-15 days after payment

Warranty period is 24 months from date of shipment

 

Storage:

Store in original unopened container at 25oC.

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